Serveur d'exploration sur le cobalt au Maghreb

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Crystal structure of bis­(azido-κN)bis[2,5-bis(pyridin-2-yl)-1,3,4-thia­diazole-κ2N2,N3]cobalt(II)

Identifieur interne : 000008 ( Maroc/Analysis ); précédent : 000007; suivant : 000009

Crystal structure of bis­(azido-κN)bis[2,5-bis(pyridin-2-yl)-1,3,4-thia­diazole-κ2N2,N3]cobalt(II)

Auteurs : Abdelhakim Laachir [Maroc] ; Fouad Bentiss [Maroc] ; Salaheddine Guesmi [Maroc] ; Mohamed Saadi [Maroc] ; Lahcen El Ammari [Maroc]

Source :

RBID : PMC:4420119

Abstract

The structure of the title compound is isotypic with that of the analogous nickel(II) complex, in which the CoN6 core shows an axially weakly compressed octa­hedral geometry as opposed to the almost regular geometry exhibited by the NiN6 octa­hedron.


Url:
DOI: 10.1107/S2056989015006544
PubMed: 25995853
PubMed Central: 4420119


Affiliations:


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PMC:4420119

Le document en format XML

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<title xml:lang="en">Crystal structure of bis­(azido-κ
<italic>N</italic>
)bis[2,5-bis(pyridin-2-yl)-1,3,4-thia­diazole-κ
<sup>2</sup>
<italic>N</italic>
<sup>2</sup>
,
<italic>N</italic>
<sup>3</sup>
]cobalt(II)</title>
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<country xml:lang="fr">Maroc</country>
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<sup>2</sup>
<italic>N</italic>
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<sup>3</sup>
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<p>The structure of the title compound is isotypic with that of the analogous nickel(II) complex, in which the CoN
<sub>6</sub>
core shows an axially weakly compressed octa­hedral geometry as opposed to the almost regular geometry exhibited by the NiN
<sub>6</sub>
octa­hedron.</p>
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   |wiki=    Wicri/Terre
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   |clé=     PMC:4420119
   |texte=   Crystal structure of bis­(azido-κN)bis[2,5-bis(pyridin-2-yl)-1,3,4-thia­diazole-κ2N2,N3]cobalt(II)
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